Polynuclear ampyrone based 3d coordination clusters
نویسندگان
چکیده
منابع مشابه
Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects†
This work addresses and enlightens synthetic aspects derived from our effort to systematically construct isoskeletal tetranuclear coordination clusters (CCs) of the general formula [TR2Ln2IJLX)4IJNO3)2IJsolv)2] possessing a specific defected dicubane topology, utilizing various substituted Schiff base organic ligands (H2LX) and Ni /Co and DyIJOTf)3 salts. Our synthetic work is further supported...
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The synthesis of hexanuclear lanthanide hydroxo complexes by controlled hydrolysis led to polymorphic compounds. The hexanuclear entities crystallize in four different ways that depend on the extent of their hydration. The four structures can be described as hexanuclear lanthanide entities with formula [Ln(6)(mu(6)-O)(mu(3)-OH)(8)(NO(3))(6)(H(2)O)(12)](2+). Two additional NO(3)(-) ions intercal...
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ژورنال
عنوان ژورنال: CrystEngComm
سال: 2018
ISSN: 1466-8033
DOI: 10.1039/c7ce02093g